官方网页 科教人文：Zhang,X.Peter
官方网页科教人文Zhang,X.Peter个人资料、作品Zhang，X.Peter个人资料，教授-波士顿学院-个人资料，个人简历 Education and Trainingr 1999 – 2001 Postdoc; Massachusetts Institute of Technology (Stephen L. Buchwald)r 1996 – 1999 Postdoc; Massachusetts Institute of Technology (Stephen J. Lippard)r 1991 – 1996 Ph.D.; University of Pennsylvania (Bradford
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个人简历Education and Trainingr1999 – 2001 Postdoc; Massachusetts Institute of Technology (Stephen L. Buchwald)r1996 – 1999 Postdoc; Massachusetts Institute of Technology (Stephen J. Lippard)r1991 – 1996 Ph.D.; University of Pennsylvania (Bradford B. Wayland)r1985 – 1988 M.S.; Beijing Normal University, China (Bo-Li Liu)r1981 – 1985 B.S.; Anhui Normal University, China (Huai-Zhu Ma)rrPositions and Employmentsr2015 – Now Full Professor, Department of Chemistry, Boston Colleger2010 – 2015 Full Professor, Department of Chemistry, University of South Floridar2006 – 2010 Associate Professor, Department of Chemistry, University of South Floridar2001 – 2006 Assistant Professor, Department of Chemistry, University of Tennesseer1999 – 2001 Postdoctoral Associate, Department of Chemistry, MITr1996 – 1999 NIH Postdoctoral Fellow, Department of Chemistry, MITrrHonors and Awardsr2009 Thieme Chemistry Journal Awardr2008 University Research Merit Award, University of South Floridar2007 Outstanding Research Achievement Award, University of South Floridar2006 NSF CAREER Awardr2005 Chancellor’s Professional Development Award, University of Tennesseer2003 ORAU Ralph Powe Junior Faculty Awardr1996 NIH Postdoctoral Fellow研究领域”””基于金属-卟啉配合物的不对称“金属自由基催化”反应（MRC）r包含：设计并合成一系列手性金属-卟啉自由基催化剂；r将金属自由基催化（MRC)应用于立体选择性的环化反应、C-H 官能化反应、串联反应等，并应用于构建复杂分子；r通过电子顺磁共振（EPR)等手段研究反应活性中间体的结构与性质。”””近期论文Li, C.-Q.; Lang, K.; Lu, H.-J.; Hu, Y.; Cui, X.; Wojtas, L.; Zhang, X. P. “Catalytic Radical Process for Enantioselective Amination of C(sp3)–H Bonds” Angew. Chem. Int. Ed. 2018,10.1002/anie.201808923. [Link]rrWen, X.; Wang, Y.; Zhang, X. P. “Enantioselective Radical Process for Synthesis of Chiral Indolines by Metalloradical Alkylation of Diverse C(sp3)-H Bonds” Chem. Sci. 2018, 9, 5082–5086. rrWang, Y.; Wen, X.; Cui, X.; Zhang, X. P. “Enantioselective Radical Cyclization for Construction of 5-Membered Ring Structures by Metalloradical C-H Alkylation” J. Am. Chem. Soc. 2018, 140, 4792–4796. rrWang, Y.; Zhang, X. P. “[Co(3,5-Di-t-Bu-QingPhyrin)]” e-EROS, John Wiley & Sons, 2018; DOI: 10.1002/047084289X.rn02204. rrWang, Y.; Zhang, X. P. “[Co(3,5-Di-t-Bu-Xu(2′-Naph)Phyrin)]” e-EROS, John Wiley & Sons, 2018; DOI: 10.1002/047084289X.rn02203. rrWang, Y.; Zhang, X. P. “[Co(3,5-Di-t-Bu-ChenPhyrin)]” e-EROS, John Wiley & Sons, 2018; DOI: 10.1002/047084289X.rn02202. rrWang, Y.; Zhang, X. P. “[Co(3,5-Di-t-Bu-IbuPhyrin)]” e-EROS, John Wiley & Sons, 2018; DOI: 10.1002/047084289X.rn02201. rrWang, Y.; Zhang, X. P. “[Co(2,6-DiMeO-ZhuPhyrin)]” e-EROS, John Wiley & Sons, 2018; DOI: 10.1002/047084289X.rn02200. rrJiang, H.-L.; Lang, K.; Lu, H.-J.; Wojtas, L.; Zhang, X. P. “Asymmetric Radical Bicyclization of Allyl Azidoformates via Cobalt(II)-Based Metalloradical Catalysis” J. Am. Chem. Soc. 2017, 139, 9164–9167. rrXu, X.; Wang, Y.; Cui, X.; Wojtas, L.; Zhang, X. P. “Metalloradical Activation of α-Formyldiazoacetates for Catalytic Asymmetric Radical Cyclopropanation of Alkenes” Chem. Sci. 2017, 8, 4347–4351. rrWang, Y.; Wen, X.; Cui, X.; Wojtas, L.; Zhang, X. P. “Asymmetric Radical Cyclopropanation of Alkenes with In Situ-Generated Donor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis” J. Am. Chem. Soc. 2017, 139, 1049–1052. rrPegis, M. L.; McKeown, B. A.; Kumar, N.; Lang, K.; Wasylenko, D. J.; Zhang, X. P.; Raugei, S.; Mayer, J. M. “Homogenous Electrocatalytic Oxygen Reduction Rates Correlate with Reaction Overpotential in Acidic Organic Solutions” ACS Cent. Sci. 2016, 2, 850–856. rrJiang, H.-L.; Lang, K.; Lu, H.-J.; Wojtas, L.; Zhang, X. P. “Intramolecular Radical Aziridination of Allylic Sulfamoyl Azides via Co(II)-Based Metalloradical Catalysis: Effective Construction of Strained heterobicyclic Structures” Angew. Chem. Int. Ed. 2016, 55, 11604–11608. rrLu, H.-J.; Lang, K.; Jiang, H.-L.; Wojtas, L.; Zhang, X. P. “Intramolecular 1,5-C(sp3)–H Radical Amination via Co(II)-Based Metalloradical Catalysis for Five-Membered Cyclic Sulfamides” Chem. Sci. 2016, 7, 6934–6939. rrLiu, Q.-J.; Wang, L.-J.; Kang, Q.-K.; Zhang, X. P.; Tang, Y. “Cy-SaBOX/Copper(II)-Catalyzed Highly Diastereo- and Enantioselective Synthesis of Bicyclic N,O Acetals” Angew. Chem. Int. Ed. 2016, 55, 9220–9223. rrLiu, Q.-J.; Yan, W.-G.; Wang, L.-J.; Zhang, X. P.; Tang, Y. “One-Pot Catalytic Asymmetric Synthesis of Tetrahydrocarbazoles” Org. Lett. 2015, 17, 4014–4017. rrGoswami, M.; Lyaskovskyy, V.; Domingos, S. R.; Buma, W. J.; Woutersen, S.; Troeppner, O.; Ivanovic-Burmazovic, I.; Lu, H.-J.; Cui, X.; Zhang, X. P.; Reijerse, E. J.; DeBeer S.; van Schooneveld, M. M.; Pfaff, F.; Ray, K.; de Bruin, B. “Characterization of Porphyrin-Co(III)-‘Nitrene Radical’ Species Relevant in Catalytic Nitrene Transfer Reactions” J. Am. Chem. Soc. 2015, 137, 5468–5479. rrSubbarayan, V.; Jin, L.-M., Cui, X.; Zhang, X. P. “Room Temperature Activation of Aryloxysulfonyl Azides by [Co(II)(TPP)] for Selective Radical Aziridination of Alkenes via Metalloradical Catalysis” Tetrahedron Lett. 2015, 56, 3431–3434. rrCui, X.; Xu, X.; Jin, L.-M.; Wojtas, L.; Zhang, X. P. “Stereoselective Radical C–H Alkylation with Acceptor/Acceptor-Substituted Diazo Reagents via Co(II)-Based Metalloradical Catalysis” Chem. Sci. 2015. 6, 1219–1224. rrJin, C.-Y., Decker, A. M.; Huang, X.-P.; Gilmour, B. P.; Blough, B. E.; Roth, B. L.; Hu, Y.; Gill, J. B.; Zhang, X. P. “Synthesis, Pharmacological Characterization, and Structure-Activity Relationship Studies of Small Molecular Agonists for the Orphan GPR88” ACS Chem. Neurosci. 2014, 5, 576–587. rrLu, H.-J.; Li, C.-Q.; Jiang, H.-L.; Lizardi, C. L.; Zhang, X. P. “Chemoselective Amination of Propargylic C(sp3)−H Bonds via Co(II)-Based Metalloradical Catalysis” Angew. Chem. Int. Ed. 2014, 53, 7028–7032.
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